SAFETY DATA SHEET Z33 Vulcanising Solution
Recycled rubber made using Dunlop technology and machinery
Date of Issue: 09/12/14
Date of Review: 01/07/22
Reasons for Issue: Update Regulatory Information.
Download the latest version (01/07/22) of the datasheet (.PDF format)
TABLE OF CONTENTS
- IDENTIFICATION
- HAZARDS IDENTIFICATION
- COMPOSITION
- FIRST AID MEASURES
- FIRE FIGHTING MEASURES
- ACCIDENTAL RELEASE MEASURES
- HANDLING AND STORAGE
- EXPOSURE CONTROLS: PERSONAL PROTECTION
- PHYSICAL AND CHEMICAL PROPERTIES
- STABILITY AND REACTIVITY
- TOXICOLOGICAL INFORMATION
- ECOLOGICAL INFORMATION
- DISPOSAL CONSIDERATIONS
- TRANSPORT INFORMATION
- REGULATORY INFORMATION
- OTHER INFORMATION
1. IDENTIFICATION
Product Name: Z33 Vulcanising Solution
Other Names: Aliphatic hydrocarbon
Chemical ‘Family: Aliphatic, cycloparaffinic hydrocarbon
Molecular formula: N/A
Recommended Use: Retreading of TBR, LT, & PC casings & vulcanisation of conveyor belts
Supplier:
Rubber Solutions Asia-Pacific Ltd
ABN: PO Box 40-604 Upper Hutt Street
Address: South Pacific Industrial Park, Railway Ave, Upper Hutt
Telephone: 64-4-5285071
Fax: 64-4-5285074
Emergency phone: 027-2274026
All other inquiries: 027-2274026
2. HAZARDS IDENTIFICATION
Product is classified as hazardous according to Schedules 1 to 6 of the Hazardous Substances (minimum Degrees of Hazard) Regulations 2001 of the HSNO Act, 1996.
HSNO Classifications:
3.1B, 6.1E, 6.3A, 6.9, 9.1B
Signal word: DANGER
Risk Phrases:
- HH03 Harmful if swallowed
- HH20 May cause an allergic skin reaction
- HH32 Harmful if inhaled
- HP44 Extremely flammable liquid & vapour
- HH19 Causes eye irritation
Safety Phrases:
- PP10 Keep away from ignition sources such as heat/sparks/open flame/hot surfaces. No smoking
- PP31 Keep cool & protect from sunlight
- PP44 Use explosion-proof electrical/ventilating/lighting equipment
- PP60 Do not breathe dust/fumes/gas/mist/vapours/spray
- P243 Take precautionary measures against static discharge
- P261 Do not breathe dust/fumes/gas/mist/vapours/spray
- P264 Wash hands thoroughly after using
- P271 Use only outdoors or in well-ventilated area
- P273 Avoid release to the environment
- P280 Use protective gloves, protective clothing and eye protection
- PP61 Call a POISON CENTRE or Doctor if exposed or if you feel unwell
Dangerous Goods Classification: 3 Poisons Schedule
3. COMPOSITION
Information on Ingredients
Chemical Ingredient | CAS No | Proportion (%v/v) |
---|---|---|
Heptanes | 142-82-5 | 50.0 - 60.0 |
Cyclohexane | 110-82-7 | 20.0 - 30.0 |
n-hexane | 110-54-3 | <2 |
Methyl Cyclohexane | 108-87-2 | <20 |
Octane | 111-65-9 | <5 |
Rubber Compound | 8.0 |
4. FIRST AID MEASURES
For advice, contact Poisons Information Centre (Phone: 0800 Poison 764 766) or a doctor.
Ingestion:
If swallowed do NOT induce vomiting...give water. Use mouth to nose rather than mouth to mouth with artificial respiration .Obtain medical attention
Eye Contact:
Hold eyelids apart & flush the eye continuously with running water. Continue for at least 15 minutes or till advised by National Poisons Centre (0800 746 766)
Skin Contact:
If skin or hair contact occurs, remove contaminated clothing & flush as above with water
Inhalation;
Move to fresh air immediately. Keep person warm and at rest in a position comfortable for breathing. If respiratory irritation, dizziness, nausea or unconsciousness occurs, seek immediate medical assistance. Begin artificial respiration if breathing stopped
First Aid facilities:
Provide eye baths & safety showers close to areas where splashing may occur.
Medical Attention:
Treat according to symptoms. Gastric lavage may be indicated if ingested. If ingested, material may be aspirated into the lungs and cause chemical pneumonitis, treat appropriately. General measures should be taken to control acidosis & maintain urine output.
This product contains light hydrocarbon material, or a component, may be associated with cardiac sensitisation following very high exposure (well above occupational exposure limits) or with concurrent exposure to high stress levels or heart stimulating substances like epinephrine. Administration of such substances should be avoided.
5. FIRE FIGHTING MEASURES
Evacuate area. Shut off product that may fuel a fire if safe to do so. Allow trained personnel to attend a fire in progress, providing firefighters with this Safety Data Sheet. Prevent extinguishing media from escaping to drains and waterways.
Suitable extinguishing media:
Dry chemical, Carbon Dioxide or foam
Hazards from combustion products:
Carbon Dioxide & carbon monoxide
Precautions for fire fighters and special protective equipment:
Full protective clothing, and in enclosed spaces wear self-contained breathing apparatus (SCBA). Vapour is flammable and heavier than air. Vapour may travel across the ground and reach remote sources of ignition causing a flashback fire danger
Hazchem Code: 3YE
6. ACCIDENTAL RELEASE MEASURES
Emergency Procedures
- Prevent fluid from escaping to drains & waterways.
- Contain leaking packaging in a containment drum.
- Prevent vapours from building up in confined spaces.
- Ensure drain valves are closed
Methods and materials for containment Major Land Spill
- Eliminate sources of ignition
- Warn occupants of downwind areas of possible fire & explosion hazard
- Prevent liquid from entering sewers, watercourses, or low-lying areas
- Keep public away from the area
- Shut off the source of the spill if possible to do so
- Advise authorities if substance has entered a watercourse or sewer or has contaminated soil or vegetation
- Take measures to minimise the effect on ground water
- Contain spilled liquid with sand or earth
- Consult an expert on disposal of recovered material & ensure conformity to disposal rules
Major Water Spill
- Eliminate any source of ignition
- Warn occupants & shipping in downwind areas of possible fire & explosion hazard
- Notify the port or relevant authority & keep public away
- Shut off the source of spill if possible & safe to do so
- Confine spill if possible
- Remove the product from the surface by skimming or with absorbent material
- Consult an expert on disposal & ensure conformity to local regulations of disposal
7. HANDLING AND STORAGE
Precautions tor safe handling
This product is flammable. Do NOT open near open flame, sources of heat or ignition No smoking Keep container closed & handle with care.
Conditions for safe storage
Store in a cool, dry place away from direct sunlight. Do not cut, heat or weld containers
Incompatible materials
Butyl Rubber, EPDM, Polystyrene
8. EXPOSURE CONTROLS: PERSONAL PROTECTION
National Exposure Standards
Time weighted average (TWA) is 600mg/m3 (159 ppm)
Short term exposure limit (STEL) is not specified, which is the max allowable exposure concentration at any time
Biological limit values
For guidance; n-hexane in urine, 0.4 mg/L (as 2,5-hexanedione without hydrolysis)
Engineering Controls: Ventilation
The use of local exhaust ventilation is recommended to control process emissions near the source. Lab samples should be handled in a fume hood. Use explosion proof ventilation equipment.
Personal Protective Equipment Respiratory Protection:
Where concentrations in air may exceed the limits described in the National Exposure Standards it is recommended to use a half-face mask to avoid inhalation. Type ‘A’ filter material to be used
Eye Protection:
Always use safety glasses or face shield when handling this product
Skin/Body Protection:
Long sleeves & long trousers recommended with enclosed footwear or safety boots
Chemical resistant gloves to be used
9. PHYSICAL AND CHEMICAL PROPERTIES
Property | Unit of measurement | Typical value |
---|---|---|
Appearance | Black viscous liquid | |
Boiling Point | ℃ | 75-115 |
Flash Point | ℃ | -15 |
Density @ 15℃ | g/ml | 0.72 |
Vapour Pressure @ 20℃ | kPa | N/A |
Explosive Limits (LEL-UEL) | % | 1-7 |
Vapour Density @ 20℃ | kPa | N/A |
Autoignition Temperature | ℃ | >200 |
Viscosity @ 20℃ | cSt | N/A |
Percent Volatiles | % | 100 |
Solubility with Water | %w/w | <0.10 |
The values listed are indicative of this product’s physical and chemical properties. For a full product specification, please consult the Product Data Sheet.
10. STABILITY AND REACTIVITY
Chemical Stability
Stable @ room temperature
Conditions to avoid
Sources of heat & ignition, open flame
Hazardous decomposition products
No decomposition products except on burning
Hazardous reactions
Oxidising agents, mineral acids. phosphorous & chlorine
11. TOXICOLOGICAL INFORMATION
Acute Effects
Ingestion
Produces hallucinations & narcotic effects...drowsiness with volume ingestion. .fatigue, loss of appetite, paresthesia in distal extremities, muscle weakness, cold pulsation in extremities, blurred vision, headache & nausea. Vomiting may cause this product to be aspirated to the lungs resulting ln chemical pneumonitis or pulmonary oedema
Eye Contact
This product is irritating to the eyes but will not permanently damage eye tissue
Skin Contact
Irritating...may result in cracking & dryness
Inhalation
Irritating to respiratory tract. Large concentrations may cause muscle weakness, tingling extremities, blurred vision, headaches, nausea, loss of appetite, hallucinations, act as an anaesthetic and may have other central nervous system effects
Chronic Effects
Possible damage to peripheral nervous system, possibly arms & legs
Other Health Effects Information
Contains n-hexane with experimental teratogenic & reproductive effects Use in conjunction with MEK will greatly enhance effects
Toxicological Information
n-hexane: 28710mg/kg (oral, rat)
12. ECOLOGICAL INFORMATION
Eco toxicity
Aquatic Toxicity
Fish Toxicity (rainbow trout, goldfish, bluegill). .. .LC5O(96hr). .toxic to aquatic organisms Bluegreen algae...possible with continuous exposure
Persistence/degradability
Readily biodegradable. Oxidises rapidly by photo-chemical reactions in air
Mobility
Highly volatile & rapidly evaporates to the air if released into water
13. DISPOSAL CONSIDERATIONS
Disposal Methods
Empty-packaging-to recycling, recovery or disposal through qualified contractor...ensure empty packaging allowed to dry first
Special Precautions for Landfill or Incineration
NOT suitable for landfill. Ashless & can be burned in appropriate equipment
14. TRANSPORT INFORMATION
Road and Rail Transport | Marine Transport; | Air Transport | |||
---|---|---|---|---|---|
UN No. | 3295 | UN No. | 3295 | UN No. | 3295 |
Proper Shipping Name | 100% Liquid Hydrocarbon | Proper Shipping Name | 100% Liquid Hydrocarbon | Proper Shipping Name | 100% Liquid Hydrocarbon |
DG Class | 3 | DG Class | 3 | DG Class | 3 |
Sub Risk | None | Sub Risk | None | Sub Risk | None |
Pack Group | II | Pack Group | II | Pack Group | II |
Hazchem | 3YE | Hazchem | 3YE | Hazchem | 3YE |
Dangerous Goods Segregation
Product classified as DG Class 3, packing group ll. Please consult the Land Transport Rule: DG2005 & NZS 5455: 1999 Transport of Dangerous Goods on Land for information
15. REGULATORY INFORMATION
The regulatory information is not intended to be comprehensive. Other regulations may apply to this material.
Country/Region: New Zealand
Environmental Risk Management Authority (ERMA) Group Standard Number:
Solvents (Flammable) Group Standard 2017, HSR002650
The following items have been taken from the SDS for the pure solvent and can be considered a useful guide for handling Z33.
Certified Handler: Not Required
Restriction to Workplace: Not applicable.
Signage: Threshold Quantity: 250 Litres
Fire Extinguishers: Threshold Quantity: 250 Litres
Emergency Response Plan: Threshold Quantity: 1000 Litres
Secondary containment: Threshold Quantity: 1000 Litres
Other: Location and transit depot test certification:100 litres (closed containers greater than 5 Litres); 250 Litres (closed containers up to and including 5 Litres); 50 Litres (open containers).
Hazardous atmosphere zone: 100 litres (closed containers); 25 litres (decanting); 5 Litres (open occasionally); 1 Litre (open containers in continuous use).
Inventory: NZCIC
Status: Listed
Poisons Schedule: None established
16. OTHER INFORMATION
Reasons for issue: Update Regulatory Information.
Abbreviations:
NZCIC: NZ Chemical Industry Council
CAS Number: Chemical Abstracts Number